Residence Time Distribution

15 important questions on Residence Time Distribution

What does a PFR with infinite axial dispersion behave like?

CSTR

What is the relevance of residence time distribution (RTD) in a bubble column reactor?

  • Bubble Column Reactor:
  • - Gas A and Liquid B interaction: A(G) + B(L) → B(L) + C(L).
  • Bubble Behavior:
  • - Larger bubbles rise faster.
  • - Bubble size affects residence time.
  • - Longer residence times mean more reactant transfer.
  • Importance:
  • - Individual bubble residence times matter, not just average gas phase times.

What causes residence time distribution in a packed bed reactor?

  • Non-uniform distribution of catalyst packing.
  • Differences in flow resistance.
  • Fluid may channel through sections of least resistance.
  • Not all molecules spend the same time in the reactor.
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What happens to "fluid packages" in the reactor, and how is the conversion measured?

  • Fluid packages follow diverse trajectories.
  • Unmixed packages exhibit varied composition/conversion at the outlet.
  • Conversion is measured as the average degree of conversion of all packages leaving the reactor (between t and t+Δt).

What is the response to feeding an ideal tracer pulse at \( t = 0 \) seconds?

  • Response involves the Dirac delta function.
  • All tracer is fed instantaneously as a pulse.
  • Normalization condition: \[\int_{0}^{\infty} \delta(t) \, dt = 1.\]
  • Response describes concentration change over time.

What is the meaning of E(t) in residence time distribution?

  • E(t) represents the exit age distribution function.
  • It signifies the fraction of fluid exiting the outlet with residence time between t₁ and t₁ + Δt.
  • Characterizes the variation of residence times in a reactor.
  • Used to identify issues like by-passing or dead volumes.

What does F(t) represent in the context of residence time distribution?

  • F(t) is the cumulative age distribution function.
  • Represents the fraction of fluid with residence time smaller than t₁ at the outlet.
  • Obtained through experimental methods.
  • Useful for understanding complete fluid behavior in reactors.

Why is it sufficient to use RTD for Non-Ideal Reactors

The calculation of degree of conversion is more complicated, since mixing and flow pattern are (usually) unkown, making the mass/molar balance formulation impossible.

What is a residence time distribution?

The 'packages' entering the reactor at t=0, will have different residence times in the reactor. That creates a spread in residence time which is the Residence Time Distribution.

What is the gray area of this graph?

The gray area is E(t)*dt and is the fraction of 'packages'or molecules which entered the reactor at t=0 and left the reactor between t+dt.

Why is the total area equal to 1 between t=0 and t=infinity?

It is equal to 1 because than all elements which have entered the reactor, have leaved also the reactor.

What is the formula of the Average Residence Time?

It is the area of the "property"* "probability"

What is the relevance of the variance in RTD?

Variance in RTD plays a crucial role in its analysis:
  • Quantifies the spread of data values.
  • Helps in understanding the consistency of measurements.
  • Aids in identifying potential errors or anomalies in data.
  • Enhances the accuracy of results comparison.
  • Influences the interpretation of statistical significance.

What is the F(t)-function, and what does its curve represent?

  • Cumulative RTD function, F(t): Integral of E(t).
  • Defined as: \( F(t) = \int_{0}^{t} E(t) \, dt \).
  • F(t)-curve: Illustrates cumulative distribution over time.
  • Ranges from 0 to 1 as \( t \) increases.

Feed an ideal tracer pulse to the feed at t=0, what is the RTD response of a PFR?

Signal equal pulse, but shifted in time with period Tau.

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